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石飞飞， 夏琳*， 辛振祥
(青岛科技大学 橡塑材料与工程教育部重点实验室/橡塑材料与工程山东省重点实验室，山东 青岛 266042）
摘要： 制备了杜仲胶/PBS（聚丁二酸丁二醇酯）复合材料，并研究了硫黄用量对杜仲胶/PBS复合材料力学性能和形状记忆性能的影响。结果表明：随着硫黄用量的增大，交联密度逐渐增大，力学性能下降，DSC（差示扫描量热分析）曲线上结晶熔融峰减弱，熔点降低，结晶性能下降；复合材料的形变固定率不断增加，形变回复率先增加后减小。由此，在杜仲胶/PBS共混比(质量份比)为90/10的前提下，硫黄质量份1~2份时，复合材料的综合性能较为优异。
关键词： 杜仲胶； 硫黄； 结晶； 形状记忆
中图分类号： O 063文献标志码： A
引用格式：石飞飞， 夏琳， 辛振祥. 杜仲胶/聚丁二酸丁二醇酯复合材料的制备及其性能\[J\]. 青岛科技大学学报（自然科学版）， 2017， 38（4）： 78-83.
SHI Feifei, XIA Lin, XIN Zhenxiang. Preparation and properties of shape-memory Eucommia ulmoides gum/PBS composites\[J\]. Journal of Qingdao University of Science and Technology（Natural Science Edition), 2017, 38(4)： 78-83.
Preparation and Properties of Shape-memory Eucommia Ulmoides Gum/PBS Composites
SHI Feifei, XIA Lin, XIN Zhenxiang
(Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China)
Abstract: The shape-memory Eucommia ulmoides gum/PBS composites was prepared in this paper. The mechanical properties, shape-memory performance of Eucommia ulmoides gum/PBS composites with different dosage of sulfur were mainly studied. The results showed that crosslink density and shape fixity rate of composites increased with the increasing of sulfur content, while mechanical properties, crystallization performance decreased with the increasing of sulfur content. The shape recovery first increased and then decreased with the increasing of sulfur content. Therefore, the comprehensive properties of composites were excellent when sulfur amount was 1~2 phr， and blend ratio of Eucommia ulmoides gum/PBS was 90/10.
Key words: Eucommia ulmoides gum; sulfur; crystallization; shape-memory
收稿日期： 2016-09-26
基金项目： 国家自然科学基金委员会青年科学基金项目(51303092,51273098).
作者简介： 石飞飞(1989—)，女，硕士研究生.*通信联系人.
文章编号： 1672-6987（2017）04-0078-06； DOI： 10.16351/j.1672-6987.2017.04.012
