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功能化石墨烯及其聚苯乙烯复合材料的制备及其性能

作者:时间:2017-08-24点击数:

PDF全文下载:2017040084

莫志超, 赵健*

(青岛科技大学橡塑材料与工程教育部重点实验室/橡塑材料与工程山东省重点实验室,山东 青岛 266042)

摘要: 利用苯乙烯作为液相,超声剥离鳞片石墨,在石墨烯片层表面引发苯乙烯原位聚合,最终得到聚苯乙烯修饰的石墨烯片层。为测试该功能化石墨烯的填充效果,通过溶液共混的方法制得功能化石墨烯聚苯乙烯复合材料。测试表明:功能化石墨烯片层能够均匀稳定地分散于聚苯乙烯基体中,且经功能化石墨烯增强的聚苯乙烯复合材料的热稳定性、拉伸性能以及动态力学性能均有所提高。

关键词: 功能化石墨烯; 聚苯乙烯复合材料; 热稳定性; 机械性能; 动态力学性能

中图分类号:  TQ 31文献标志码: A

引用格式:莫志超, 赵健. 功能化石墨烯及其聚苯乙烯复合材料的制备及其性能\[J\]. 青岛科技大学学报(自然科学版), 2017, 38(4): 84-89.

MO Zhichao, ZHAO Jian. Preparation and properties of functionalized graphene and its polystyrene composites\[J\]. Journal of Qingdao University of Science and Technology(Natural Science Edition), 2017, 38(4): 84-89.

Preparation and Properties of Functionalized Graphene and Its Polystyrene Composites

MO Zhichao, ZHAO Jian

 (Key Laboratory of Rubber Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber Plastics,Qingdao University of Science and Technology, Qingdao 266042, China)

Abstract: In this paper, we stripped flaky graphite in a liquid of styrene with ultrasonic, and the in situ polymerization of styrene was initiated on the surface of graphene layer, the graphene layers modified by polystyrene were finally obtained. Meanwhile, polystyrene and functionalized graphene composites were obtained with the solution blending method. It is shown that functional graphene can steadily and uniformly dispersed in the polystyrene, and polystyrene composites enhanced by functional graphene made a difference to its thermal stability, tensile property and dynamic mechanical property.

Key words: funtional graphene; polystyrene composite; thermal stability; mechanical property; dynamic mechanical property

收稿日期:    2016-03-17

基金项目: 国家自然科学基金项目(51073082,51373088).

作者简介: 莫志超(1990—),男,硕士研究生.*通信联系人.

文章编号: 1672-6987(2017)04-0084-06; DOI: 10.16351/j.1672-6987.2017.04.013

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