PDF全文下载：
201901015.pdf
文章编号： 16726987（2019）01009108； DOI： 10.16351/j.16726987.2019.01.015
吕阳， 张茂林， 史新妍
*(青岛科技大学 高分子科学与工程学院；橡塑材料与工程教育部重点实验室，山东 青岛 266042)
摘要： 选取了钛酸钾晶须（PTW）和碳纳米管（CNTs）两种一维填料分别与炭黑（N990）协同补强氟橡胶，同时探究了硅烷偶联剂KH550对填料并用体系性能的影响，并系统地研究协同补强机理。结果表明：无论是高温还是常温条件下，N990、PTW和CNTs均能提升氟橡胶（FKM）的力学性能，其中CNTs对FKM的力学性能提升更明显，而N990和PTW使FKM具有较好的压缩永久变形性能；KH550的加入有利于N990/PTW/FKM体系中填料的分散，使其力学性能大幅增加，表现出较强的协同效应，同时保持了较好的压缩永久变形性能；N990/CNTs/FKM同样表现出较强的协同效应，但其压缩永久变形性能下降。
关键词： 氟橡胶； 炭黑； 碳纳米管； 钛酸钾晶须； 协同效应
中图分类号： TQ 323.4文献标志码： A引用格式：吕阳， 张茂林， 史新妍. 炭黑与一维填料协同补强氟橡胶\[J\]. 青岛科技大学学报（自然科学版）， 2019， 40（1）： 9198.
LYU Yang，ZHANG Maolin, SHI Xinyan. Synergistic reinforcement of carbon black and onedimensional fillers in fluororubber\[J\]. Journal of Qingdao University of Science and Technology（Natural Science Edition), 2019, 40(1)： 9198.
Synergistic Reinforcement of Carbon Black and Onedimensional Fillers in Fluororubber
LYU Yang， ZHANG Maolin, SHI Xinyan
（College of Polymer Science and Engineering； Key Laboratory of RubberPlastics，Ministry of Education， Qingdao University of Science and Technology， Qingdao 266042， China）
Abstract: In this work, two kinds of onedimensional fillers of carbon nanotubes (CNTs) and potassium titanate whiskers (PTW) were selected to react with N990, and the effect of KH550 on the properties of the fillers and the mechanism of synergistic reinforcement were investigated systematically. The results showed that N990, PTW and CNTs can improve the mechanical properties of fluororubber (FKM) at high temperature and room temperature, it was more obvious for CNTs to improve the mechanical properties of FKM, but N990 and PTW can lead FKM to have a good pressure deformation performance.The addition of KH550 favored the dispersion of the fillers in the N990/PTW/FKM composite, which resulted in a strong synergistic effect, while maintaining a good compression set. The N990/CNTs/FKM composite also showed a strong synergistic effect, but the compression performance decreased.
Key words:fluororubber； carbon black； carbon nanotubes； potassium titanate whiskers； synergistic effect
收稿日期： 20180712
基金项目： 国家自然科学基金项目(51273101)；山东省高校科技计划项目（J12LA14）.
作者简介：吕阳（1995—），男，硕士研究生.*通信联系人.
