PDF全文下载：2017020042
贾云，綦琪，王许云*
（青岛科技大学化工学院；多相流体反应与分离工程山东省重点实验室，山东青岛266042）
摘要:采用循环伏安法在石墨阳极表面合成聚吡咯/碳纳米管（PPy/CNT）复合膜，将其应用到厌氧流化床微生物燃料电池（AFBMFC）中，研究AFBMFC的产电能力和污水去除率。对不同阳极进行X射线衍射（XRD）、场发射扫描电镜（FE-SEM）的表征，并用交流阻抗法（EIS）、循环伏安法（CV）考察不同电极的电化学性能。PPy/CNT膜阳极应用于AFBMFC后，电池的最大功率密度达到150.54 mW·m-2，开路电压为793.3 mV，污水COD去除率为94.51%，相对于未修饰阳极，分别提高了74.85%、25.71%和24.04%。结果表明，PPy/CNT可以作为一种导电性能较好的复合材料应用于MFC阳极中。
关键词:微生物燃料电池； 废水； 输出功率密度； 开路电压； 复合材料
中图分类号：O 646; X 382; X 703文献标志码：A
引用格式：贾云，綦琪，王许云.聚吡咯/碳纳米管膜阳极的制备及其在厌氧流化床微生物燃料电池中的应用\[J\].青岛科技大学学报（自然科学版），2017，38（2）：42-47.
JIA Yun, QI Qi, WANG Xuyun.Preparation and application of PPy/CNT composite film anode for AFBMFC\[J\].Journal of Qingdao University of Science and Technology（Natural Science Edition),2017,38(2)：42-47.
Preparation and Application of PPy/CNT Composite Film Anode for AFBMFC
JIA Yun, QI Qi, WANG Xuyun
(Multiphase Fluid Reaction and Separation Engineering Key Liberation of Shandong Province；College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China)
Abstract: Polypyrrole/carbon nanotubes (PPy/CNT) composite film anodes were prepared using electrochemical cyclic voltammetry (CV) method. The prepared anodes were applied in an anaerobic fluidized bed microbial fuel cell (AFBMFC) to examine the production of electricity and the removal rate of waste water treatment. The modified anodes were characterized by X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM). The electrochemical behavior of the modified anodes were studied by electrochemical impedance spectroscopy (EIS) and CV method . When the PPy/CNT film anode was used in the AFBMFC, the maximum output power density was up to 150.54 mW·m-2, the open circuit voltage was 793.30 mV and the COD removal rate reached 94.51%, which were 74.85%, 25.71%, and 24.04% higher than those of unmodified anode, respectively. The results showed that the PPy/CNT composite anode could serve as a kind of composite materials with better conductive properties used in the anode of MFC.
Key words: microbial fuel cell; waste water; output power density; open circuit voltage; composite materials
收稿日期：2015-08-31
基金项目：山东省自然科学基金项目(ZR2013BM012).
作者简介：贾云（1990—），女，硕士研究生.*通信联系人.
文章编号：1672-6987（2017）02-0042-06；DOI：10.16351/j.1672-6987.2017.02.006
