谢广文， 王丽娜， 李忠
(青岛科技大学 材料科学与工程学院， 山东 青岛 266042)
摘要: 硼氢化钠水解制氢过程安全、方便，是一种新型制氢技术，已成为当前制氢研究的热点之一。该技术的关键是高效催化剂的制备。金属催化剂因其高的催化活性和低的活化能，在硼氢化钠水解制氢中得到广泛研究。主要介绍了金属催化剂催化硼氢化钠水解制氢的原理，综述了金属催化剂的发展现状，提出了该过程存在的问题与对策。最后对金属催化剂的发展趋势进行了展望。
关键词: 硼氢化钠； 水解； 氢气； 金属催化剂
中图分类号： TQ 153.2 文献标志码： A
Progress in Metal Catalysts for Hydrogen Generation Through Hydrolysis of Sodium Borohydride
XIE Guangwen, WANG Lina, LI Zhong
(College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China)
Abstract: The technology of catalytic hydrolysis of sodium borohydride solution, a safe and practical way of producing hydrogen, has become one of the hotspots in the research of hydrogen generation. The preparation of efficient catalysts is the key problem of the technology. Metal catalysts have been extensively investigated in the hydrolysis of sodium borohydride due to their high catalytic activity and low activation energy. The paper introduces basic principles of catalytic hydrolysis of NaBH4 solution, reviews the development status of metal catalysts and puts forward the problems and countermeasures in the process of sodium borohydride hydrolysis. At last, the development direction of the metal catalysts is pointed out.
Key words: sodium borohydride; hydrolysis; hydrogen; metal catalysts
收稿日期： 20141031
基金项目： 山东省自然科学基金项目（ZR2011EMM005）.
作者简介： 谢广文（1965—），男，教授，博士.
