全文下载：2013060605
邵路， 徐超， 赵季若*， 冯莺
（青岛科技大学 高分子科学与工程学院；橡塑材料与工程教育部重点实验室；山东橡塑材料与工程重点实验室，山东 青岛 266042）
摘要： 以高密度聚乙烯（HDPE）为原料，采用氯化原位接枝方法制备以氯化聚乙烯(CPE)为骨架、苯乙烯(St)为支链的接枝共聚物(记作CPE-cg-St)和以氯化聚乙烯(CPE)为骨架、苯乙烯和丙烯腈单体都为支链的接枝共聚物(记作CPE-cg-AS)。研究结果表明，氯化原位接枝可制备CPE-cg-AS，CPE-cg-St，且与CPE相比，接枝共聚物的相对分子质量增大，分布变窄，有较好的力学性能。在同样接枝率下，相同氯含量下，CPE-cg-AS，CPE-cg-St的拉伸强度较CPE分别增加了26.9%、8.9%。
关键词： CPE-cg-St； CPE-cg-AS； 共聚物； 氯化原位接枝
中图分类号： O 632.12文献标志码： A
Copolymer of Styrene-acrylonitrile Grafted onto PE by In-situ Chlorinating-graft Copolymerization
SHAO Lu， XU Chao， ZHAO Ji-ruo， FENG Ying
(Key Laboratory of Rubber-plastics,Ministry of Education；Shandong Provincial Key Laboratory of Rubber-plastics；
College of Polymer Science and Engineering，Qingdao University of Science and Technology，Qingdao 266042，China)
Abstract:In this paper, two graft copolymers were prepared using the high density polyethylene (HDPE) as raw material by in-situ chlorinating graft copolymerization (ISCGC). All the skeleton of the graft copolymers was chlorinated polyethylene (CPE). One was referred to as CPE-cg-AS which branches were styrene and acrylonitrile copolymer, and the other one was CPE-cg-St which branches was styrene. The results show that the mechanical properties of CPE-cg-AS and CPE-cg-St are better than that of CPE. The number average molecular weights of the graft copolymers increase and their molecular weight distribution are narrowed compared with that of CPE. The tensile strength of CPE-cg-AS and CPE-cg-St increases by 26.9%, 8.9% than CPE, respectively.
Key words: CPE-cg-St； CPE-cg-AS； copolymer； in-situ chlorinating graft
收稿日期：2013-03-15
基金项目： 国家自然科学基金项目（51173090）；山东省自然科学基金项目（ZR2011EL009）.
作者简介： 邵路(1984— )，男，硕士研究生.*通信联系人.
