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BiVO4/GO复合光催化剂的制备及光催化性能研究

作者:时间:2014-06-11点击数:

全文下载:2013040347

谢倩, 邓爱霞, 滕谋勇, 陶绪泉, 陈维龙, 李秀春

(聊城大学 材料科学与工程学院, 山东 聊城 252000)

摘要:  采用水热的方法,通过调控pH值,制备了具有不同晶型和晶体形貌的BiVO4/GO(氧化石墨)复合可见光光催化剂,利用XRD、SEM、FT-IR和UV-Vis对样品进行表征。XRD分析显示,pH=7的条件下光催化剂呈现纯度较高的单斜白钨矿结构。以甲基橙(MO)的可见光催化降解反应为模型反应,研究了催化剂的可见光催化性能。结果表明,经GO改性的催化剂的催化能力比纯BiVO4有极大程度的提高。

关键词:   钒酸铋; 复合光催化剂; 水热法; 光催化

中图分类号:  O 643文献标志码:  A

Synthesis and Photocatalytic Properties of Visible-light-driven BiVO4/GO Composite Photocatalysts

XIE Qian, DENG Ai-xia, TENG Mou-yong, TAO Xu-quan, CHEN Wei-long, LI Xiu-chun

(School of Materials Science and Engineering, Liaocheng University, Liaocheng 252000, China)

Abstract: BiVO4/GO(grapheme oxide) with different crystalline structure and morphology were prepared under different PH values by a hydrothermal process. TheBiVO4/GO samples were characterized by means of XRD,SEM,FTIR and UV-Vis .The XRD showed that sample prepared under PH value of 7 showed the highly crystalline monoclinic scheelite structure. The photocatalytic activity was investigated using methyl orange (MO) as a photocatalytic degradation model reactant. Results showed that the GO-doped catalysts enhanced photocatalytic activities under visible-light irradiation.

Key words:  BiVO4 ;  composite photocatalyst;  hydrothermal method; photocatalysis

收稿日期: 2012-09-14

基金项目: 聊城大学大学生科技文化创新基金项目(SRT11007CL2).

作者简介:  谢倩(1977—),女,讲师.

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