PDF全文下载:2011060610
付国家, 郭庆杰*
(青岛科技大学 化工学院;清洁化工过程山东省重点实验室,山东 青岛 266042)
摘要: 研究了药用活性炭对硫酸奎宁吸附性能的影响,并采用Langmuir和Freundlich吸附等温线模型拟合了活性炭对硫酸奎宁的吸附行为。结果表明:硫酸奎宁吸附量随药用活性炭用量的增加呈上升趋势,但吸附效率却呈下降趋势。在所研究的条件下,活性炭对硫酸奎宁的吸附量随温度和初始浓度的升高而增大,在313 K吸附值最大为123.457 mg·g-1。与Freundlich吸附模型(r2f<0 r2l="">0.97),说明Langmuir模型适用于所研究的体系。
关键词: 药用活性炭; 吸附性能; 硫酸奎宁
中图分类号: O 647.3文献标志码: A
Adsorption Behavior of Quinine Sulfate onto Medicinal Activated Carbon
FU Guo-jia, GUO Qing-jie
(College of Chemical Engineering, Qingdao University of Science and Technology, Key Laboratory of Clean Chemical Processing Engineering of Shandong Province, Qingdao 266042, China )
Abstract: In this study, the adsorption effect of medicinal activated carbon for quinine sulfate(QS) removal from aqueous solutions was investigated. The adsorption behavior of QS onto medicinal activated carbon was fitted with Langmuir and Freundlich adsorption isotherm models. The results showed that an increase the dosage of activated carbon enhanced the adsorption capacity, but failed to increase the QS removal efficiency. In the studied conditions, the adsorption of QS onto activated carbon rised with increasing temperature and the initial QS concentration, and the calculated maximum adsorption capacity of activated carbon was 123.457 mg·g-1 at 313 K. Compared with Freundlich model (r2f<0 the="" experimental="" data="" indicated="" that="" adsorption="" isotherms="" were="" fitted="" well="" with="" langmuir="" equilibrium="" isotherm="" r2l="">0.97).
Key words: medicinal activated carbon; adsorption capacity; quinine sulfate
收稿日期:2011-10-11
基金项目: 国家自然科学基金项目(20876079);教育部新世纪优秀人才支持计划项目(NCET-07-0473);山东省科技攻关项目(2009GG10007001);山东省自然科学杰出青年基金项目(JQ200904).
作者简介: 付国家(1985—),男,硕士研究生.*通信联系人.