全文下载： 
202104003.pdf
文章编号： 1672-6987（2021）04-0019-08； DOI： 10.16351/j.1672-6987.2021.04.003
申优1a， 齐有啸2， 杨星3， 张波3， 万均1a*， 王新星1b
(1.青岛科技大学 a.环境与安全工程学院；b.化学与分子工程学院，山东 青岛 266042；
2.鲁南制药集团股份有限公司，山东 临沂 276000；3.贵州红星发展股份有限公司，贵州 安顺 561206)
摘要： 制备了NH2-UiO66和电化学还原氧化石墨烯（rGO）的混合材料NH2-UiO66/rGO，并将其成功地用于电化学同时检测镉离子（Cd2+）和铅离子（Pb2+）。通过采用扫描电子显微镜（SEM）、X射线衍射和各种电化学技术对材料的形貌及其电化学性质进行了表征。结果表明：NH2-UiO66/rGO具有较NH2-UiO66明显改善的电化学性质。所构建的电化学传感平台在优化条件下可以实现对Cd2+和Pb2+的灵敏检测。此外，该传感器具有良好的选择性、重现性和稳定性，在实际样品检测中也具有广阔的应用前景。
关键词： 金属有机骨架； NH2-UiO66； 纳米复合材料； 重金属离子； 电化学传感
中图分类号： TP 212.2文献标志码： A
引用格式： 申优， 齐有啸， 杨星， 等. NH2-UiO66/rGO纳米复合材料的制备及其在铅离子和镉离子电化学传感中的应用［J］. 青岛科技大学学报(自然科学版), 2021, 42(4): 19-26.
SHEN You, QI Youxiao, YANG Xing, et al. Preparation of NH2-UiO66/rGO nanocomposite and its application in electrochemical sensing of lead ions and cadmium ions［J］. Journal of Qingdao University of Science and Technology（Natural Science Edition), 2021， 42（4）： 19-26.
Preparation of NH2-UiO66/rGO Nanocomposite and Its Application in
Electrochemical Sensing of Lead Ions and Cadmium Ions
SHEN You1a, QI Youxiao2, YANG Xing3, ZHANG Bo3, WAN Jun1a, WANG Xinxing1b
(1.a.College of Environment and Safety Engineering; b.College of Chemistry and Molecular Engineering,
Qingdao University of Science and Technology, Qingdao 266042, China; 2.Lunan Pharmaceutical
Group Co., Ltd., Linyi 276000, China; 3.Guizhou Red Star Development Co., Ltd., Anshun 561206, China)
Abstract: In this paper, a mixed material of NH2-UiO66 and electrochemically reduced graphene oxide (rGO), NH2-UiO66/rGO, was prepared, and has been successfully used in the electrochemical determination of cadmium ions (Cd2+) and lead ions (Pb2+). The morphology and electrochemical properties of the material were characterized by scanning electron microscopy (SEM), X-ray diffraction and various electrochemical techniques. The results show that the electrochemical properties of the NH2-UiO66/rGO have significantly improved than NH2-UiO66. The constructed electrochemical sensing platform can realize the sensitive detection of Cd2+ and Pb2+ under optimized conditions. In addition, the sensor has good selectivity, reproducibility and stability, and has broad application prospects in actual sample detection.
Key words: metal-organic frameworks; NH2-UiO66; nanocomposite; heavy metal ions; electrochemical sensing
收稿日期： 2020-11-12
基金项目： 国家自然科学基金青年项目（21804076）；光电传感与生命分析教育部重点实验室开放基金项目（SATM201708）.
作者简介： 申优(1997—),女,硕士研究生.*通信联系人.
