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文章编号： 16726987（2018）04008006； DOI： 10.16351/j.16726987.2018.04.012
常宪增， 史新妍*
(青岛科技大学 橡塑材料与工程教育部重点实验室，山东 青岛 266042)
摘要： 采用新型环保促进剂（ACT55P），以炭黑作为补强体系，通过密炼与开炼的方法制得羧酸型丙烯酸酯橡胶（ACM）混炼胶，与传统胍类促进剂（DOTG）作对比，探究不同硫化体系对两种羧酸型ACM的影响，并研究了不同炭黑（N550）用量对胶料性能的影响。结果表明：与DOTG相比，采用ACT55P的ACM胶料的黏度较低，加工性能改善，交联程度增大，焦烧时间缩短，工艺正硫化时间延长，硫化胶的拉伸强度增强，热空气老化性提高，但压缩永久变形和撕裂性能变差；随着炭黑份数的增加，门尼黏度提高，力学性能增强，形成的填料网络越强，Payne效应越明显；当炭黑用量从55份增加至75份时，门尼黏度值和Payne效应显著增大，硫化速率下降明显，对拉伸强度增长不大，因此55份为炭黑的最佳用量。
关键词： 羧酸型丙烯酸酯橡胶； 促进剂； 炭黑补强； 力学性能
中图分类号： TQ 330.38文献标志码： A
引用格式： 常宪增， 史新妍. 配合体系对羧酸型丙烯酸酯橡胶性能的影响\[J\]. 青岛科技大学学报（自然科学版）， 2018， 39（4）： 8085.
CHANG Xianzeng, SHI Xinyan. Effect of compounding system on performance of carboxylic acid type ACM\[J\]. Journal of Qingdao University of Science and Technology（Natural Science Edition), 2018, 39(4)： 8085.
Effect of Compounding System on Performance of Carboxylic Acid Type ACM
CHANG Xianzeng, SHI Xinyan
(Key Laboratory of RubberPlastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China)
Abstract: The carboxylic acid acrylate rubber (ACM) was chosen to develop environmentfriendly accelerator contrast with the traditional guanidine accelerator and carbon black N550 (CB) reinforced vulcanizates, and the influence of different content of CB on the ACM was also investigated. The results indicated that the Mooney viscosity of ACM compounds using new accelerator was lower, increased the crosslinking density and improved the hot air aging performance. With the increase of the content of CB, the Mooney viscosity of ACM compounds was increased, the mechanical properties was enhanced, and the stronger filler network, the more obvious the Payne effect. When the amount of CB increased from 55 phr to 75 phr , the Mooney viscosity and the Payne effect increased significantly， the rate of vulcanization dreased and tensile strength did not increase obviously. So,55 phr is the best amount of CB.
Key words: carboxylic acid type ACM; accelerator; carbon black reinforcement; mechanical property
收稿日期： 20170911
基金项目： 国家自然科学基金项目(51273101).
作者简介： 常宪增（1993—），男，硕士研究生.*通信联系人.
