辛基酚磺基甜菜碱型表面活性剂的合成及性能

PDF全文下载：2017010041

丁伟，李博洋，武松，张瀚文，宋成龙

（东北石油大学化学化工学院，黑龙江大庆163318）

 摘要：甜菜碱型表面活性剂在油田三次采油中具有广泛应用前景，其优良的驱油效果受到极大关注。本实验以精细合成辛基酚作为原料经过一系列反应得到磺基甜菜碱型表面活性剂，对产物进行了红外光谱的分析表征。经过测试证明：该表面活性剂具有较低的界面张力（1.5×10-3 mN·m-1），良好的表面性能（临界胶束浓度cmc为1.58×10-3 mol·L-1，表面张力γcmc为28.3 mN·m-1）及优异的乳化性能和吸附性能。

关键词：辛基酚；甜菜碱型；表面活性剂；界面张力；表面张力；乳化性能；吸附性能

中图分类号：TQ 423.12文献标志码：A

引用格式：丁伟，李博洋，武松，等.辛基酚磺基甜菜碱型表面活性剂的合成及性能［J］.青岛科技大学学报(自然科学版), 2017, 38(1): 4147.

DING Wei, LI Boyang, WU Song, ZHANG Hanwen，el al.Properties and synthesis of octyl phenol sulfobetaine type surfactant［J］.Journal of Qingdao University of Science and Technology（Natural Science Edition), 2017, 38(1): 4147.

Properties and Synthesis of Octyl Phenol Sulfobetaine Type Surfactant 

DING Wei, LI Boyang, WU Song, ZHANG Hanwen, SONG Chenglong

(Department of Chemistry and Chemical Engineering，Northeast Petroleum University，Daqing 163318，China)

Abstract: The type of betain surfactant has wide application foreground in the teriary recovery of oil field.The favorable effect of oil displacement has drew many attention.The experiment is based on the octyl phenol which has fine synthesised by us as raw material.With a series of reactions,we obtained a new sulfobetaine type surfactant which has a new formation that has been verified by IR.Some other tests indicate that this surfactant has low interfacial tension(1.5×10-3 mN·m-1),good surface properties (cmc=1.58×10-3mol·L-1，γcmc=28.39 mN·m-1)and excellent emulsifying properties，adsorption properties.

Key words:  octyl phenol；betain；surfactant;  interfacial tension；surface tension；emulsifying performance；adsorption properties

 收稿日期：20151021

基金项目：十二五国家重大专项项目（2011ZX05011004）；黑龙江省自然科学基金重点项目（ZJG0507）.

作者简介：丁伟（1964—），男，教授，博士生导师。

文章编号：16726987（2017）01004106；DOI：10.16351/j.16726987.2017.01.007