全文下载：2012.020126
付国家， 张建社， 郭庆杰*
（青岛科技大学 化工学院； 清洁化工过程山东省重点实验室， 山东 青岛 266042）
摘要:采用植物废弃物核桃壳为原料，以化学-物理耦合活化法制备了核桃壳活性炭，考察了磷酸浓度、活化温度、活化时间对核桃壳活性炭碘值、亚甲基蓝吸附值和烧失率的影响。结果表明，最佳制备条件为：磷酸质量分数85%，活化温度900 ℃，活化时间3 h。在此制备条件下，核桃壳活性炭的比表面积为1 241.81 m2·g-1，吸附累积总孔容为0.90 cm3·g-1，最可几孔径分布为1.62 nm。采用扫描电子显微镜、透射电子显微镜、比表面积测定仪以及红外光谱仪对核桃壳活性炭的表面形貌、孔结构及表面官能团进行了分析。
关键词:活性炭； 核桃壳； 耦合活化； 孔结构
中图分类号: TQ 424.1+9文献标志码： A
Preparation and Characterization of Activated Carbon from Walnut Shell by Coupled Physiochemical Activation
FU Guo-jia, ZHANG Jian-she, GUO Qing-jie
(College of Chemical Engineering； Key Laboratory of Clean Chemical Processing Engineering of
Shandong Province, Qingdao University of Science and Technology，Qingdao 266042, China )
Abstract:Activated carbons were prepared by phosphoric acid activation combined with carbon dioxide activation from plant waste walnut shell. The effects of phosphoric acid concentration, activation temperature and activation time on iodine value, methylene blue adsorption value and burn-off were investigated in detail. The optimal activation conditions are determined as: phosphoric acid concentration 50%, activation temperature 900 ℃, activation time 3 h, under which a specific surface of 1 241.81 m2·g-1, adsorption cumulative pore volume of 0.90 cm3·g-1, the most probable pore size of 1.62 nm could be reached. The surface morphology, structure of pore and surface functional groups of the prepared activated carbon were characterized with scan electric microscope, transmission electron microscope, surface area and porosity analyzer, and FT-IR spectra, respectively.
Key words:activated carbon; walnut shell; coupled activation; pore structure
收稿日期:2011-09-14
基金项目: 教育部新世纪优秀人才支持计划项目(NCET-07-0473)；山东省科技攻关项目(2009GG10007001)；山东省自然科学杰出青年基金项目(JQ200904).
作者简介: 付国家(1985—)，男，硕士研究生.*通信联系人.
