PDF全文下载：2011060576
席玉蕾， 叶庆国*
（青岛科技大学 化工学院，山东 青岛 266042）
摘要： 选用三氟乙酸铜的盐溶液，以邻菲罗啉为配体，首次合成了三氟乙酸铜的邻菲罗啉配合物，并选用乙醇/乙酸乙酯混合溶剂，水浴培养得到蓝色块状晶体。利用高斯软件对其可能结构进行了模拟计算，并通过红外表征证实了模拟结果的准确性，确定了合成配合物的结构式为\[Cu(C12H8N2)2H2O\](CF3COO)2。
关键词： 三氟乙酸铜； 邻菲罗啉； 晶体配合物； 高斯模拟
中图分类号： O 641.4文献标志码： A
Synthesis of Complex \[Cu(C12H8N2)2H2O\](CF3COO)2
XI Yu-lei, YE Qing-guo
(College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China)
Abstract: \[Cu(C12H8N2)2H2O\](CF3COO)2 was first synthesized by the salt of three fluorine copper and the ligand of 1,10-Phenanthroline, and its blue massive crystals was obtained by water bath training in the ethanol/ethyl acetate mixed solvent. The possible structures were simulated by the Gaussian software, and the accuracy of the simulation result was confirmed through the infrared characterization.
Key words: three fluorine copper; 1,10-phenanthroline; crystal complexes; gaussian simulation
收稿日期：2011-09-01
作者简介： 席玉蕾(1987—)，女，硕士研究生. *通信联系人.
