全文下载： 
202304002.pdf
文章编号： 1672-6987（2023）04-0018-10； DOI： 10.16351/j.1672-6987.2023.04.002
李浩然1， 赵震2， 冯祥砚2， 颜博1， 唐林生1,2*(1.青岛科技大学 化工学院，山东 青岛 266042； 2.山东省环境友好大分子阻燃材料工程实验室，山东 潍坊 262715）
摘要： 采用固相合成法，通过六羟甲基三聚氰胺(HMM)与赛克醚化和缩聚合成了赛克改性三聚氰胺甲醛树脂(简称赛改树脂)，并通过红外光谱和固体13C NMR表征了其结构。其较佳的合成条件：n(HMM)∶n(赛克)=1∶250，反应温度130 ℃，反应时间4 h。在此条件下，产品的质量产率为862%，水溶性为0177 g·（100 mL）-1水；赛克树脂的初始热稳定性、成炭能力和对聚丙烯（PP）的协效阻燃作用均好于HMM和赛克，例如HMM、赛克和赛改树脂的T5%分别为149、245和291 ℃，750 ℃时的残余率分别为948%、030%和1214%，阻燃PP达到V-0级时，聚磷酸铵（APP）/赛改树脂、APP/HMM和APP/赛克的最小添加量分别为24%、34%和26%。PP/APP/赛改树脂的耐水性也明显好于PP/APP/赛克。
关键词： 三聚氰胺甲醛树脂； 赛克； 改性； 合成； 协效阻燃作用
中图分类号： TQ 325文献标志码： A
引用格式： 李浩然， 赵震， 冯祥砚， 等. 赛克改性三聚氰胺甲醛树脂的合成及协效阻燃作用［J］. 青岛科技大学学报(自然科学版), 2023, 44(4): 18-27.
LI Haoran, ZHAO Zhen, FENG Xiangyan, et al. Synthesis and synergistic flame retardancy of the melamine formaldehyde resin modified with THEIC［J］. Journal of Qingdao University of Science and Technology（Natural Science Edition), 2023， 44（4）： 18-27.
Synthesis and Synergistic Flame Retardancy of the Melamine
Formaldehyde Resin Modified with THEIC
LI Haoran1, ZHAO Zhen2, FENG Xiangyan2, YAN Bo1, TANG Linsheng1,2
(1.College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
2.Shandong Engineering Laboratory of Environment-friendly Macromolecular Flame Retardant Material，Weifang 262715, China)
Abstract: The melamine formaldehyde resin modified with THEIC (resin modified with THEIC in brief) was synthesized through the etherification and condensation of hexahydroxymethyl melamine (HMM) with THEIC by using solid phase synthesis method, and its structure was characterized by infrared spectroscopy and solid 13 C NMR. The better synthesis conditions were as follows: n(HMM)∶n(THEIC)=1∶250, reaction temperature being 130 ℃ and reaction time being 4 h. Under the above conditions, the mass yield of the product was 862% and the water solubility was 0177 g·（100 mL）-1. The initial thermal stability, charring ability and synergistic flame retardancy in polypropylene（PP ）of the resin modified with THEIC are better than those of HMM and THEIC, for example, the T5% of HMM, THEIC and the resin are 149, 245 and 291 ℃, respectively, and the residual at 750 ℃ is 948%, 030% and 1214%, respectively, when the flame retardant PP reaches V-0 level, the minimum of ammonium polyphosphate(APP)/the resin, APP/HMM and APP/THEIC were 24%, 34% and 26%, respectively. The water resistance of PP/APP/the resin is also significantly superior to that of PP/APP/THEIC.
Key words: melamine formaldehyde resin; modification; THEIC; synthesis; synergistic flame retardancy
收稿日期： 2022-09-24
基金项目： 国家自然科学基金项目（21878165）.
作者简介： 李浩然（1999—），男，硕士研究生.*通信联系人.
