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文章编号： 1672-6987（2023）04-0028-06； DOI： 10.16351/j.1672-6987.2023.04.003
刘文昊1， 王盛海2， 冯祥砚2, 赵震2， 唐林生1,2*(1. 青岛科技大学 化工学院，山东 青岛 266042；
2. 山东省环境友好大分子阻燃材料工程实验室，山东 潍坊262715)
摘要： 以NaOH为缚酸剂，水为溶剂，在OP-10存在下，通过三聚氯氰与哌嗪缩聚合成了哌嗪基超支化三嗪成炭剂，并通过热重分析研究了它们的热稳定性和成炭性。结果表明，其较佳合成条件：n(三聚氯氰)∶n(哌嗪)∶n(NaOH)=10∶15∶30，w(三聚氯氰)∶w(水)∶w(OP-10)=10∶27∶009，10~15 ℃缩合25 h，50~55 ℃缩合25 h，90~95 ℃缩聚6 h。在以上条件下，产品的产率、氯含量和水溶性分别为973%、055%和021 g·（100 mL）-1水，产品的热稳定性和成炭性良好。该合成方法不采用低沸点溶剂，不仅减少了污染、安全性更好，而且合成工艺和设备更加简单。
关键词： 哌嗪； 超支化三嗪成炭剂； 合成； 表征； 热稳定性
中图分类号： T 325.2文献标志码： A
引用格式： 刘文昊， 王盛海， 冯祥砚, 等. 哌嗪基超支化三嗪成炭剂的合成及表征［J］. 青岛科技大学学报(自然科学版), 2023, 44(4): 28-33.
LIU Wenhao, WANG Shenghai, FENG Xiangyan, et al. Synthesis and characterization of the piperazine-based hyperbranched triazine charring agent［J］. Journal of Qingdao University of Science and Technology（Natural Science Edition), 2023， 44（4）： 28-33.
Synthesis and Characterization of the Piperazine-based
Hyperbranched Triazine Charring Agent
LIU Wenhao1, WANG Shenghai2, FENG Xiangyan2, ZHAO Zhen2, TANG Linsheng1,2
(1.College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China；
2.Shandong Engineering Laboratory of Environment-friendly Macromolecular Flame Retardant Material，Weifang 262715, China)
Abstract: The piperazine-based hyperbranched charring agent was synthesized through condensation polymerization of cyanuric chloride with piperazine by using water as a solvent and NaOH as an acid binding agent in the presence of OP-10, and its thermal stability and charring property were studied by thermogravimetric analysis. The results show that its optimum synthesis conditions are as follows∶ n(cyanuric chloride)∶n(diamine)∶n(sodium hydroxide)=10∶15∶30,w(cyanuric chloride)∶w(water)∶w(OP-10)=10∶27∶009, the condensation time at 10—15 ℃ being 25 h, the condensation time at 50—55 ℃ being 25 h, and the condensation polymerization time at 90—95 ℃ being 6 h. Under the above conditions, the product yield is 973%, its chlorine content and water solubility are respectively 055% and 021 g·（100 mL）-1, and its thermal stability and charring property are good. The synthesis method without low-boiling organic solvents has some merits such as less environmental pollution, better safety, simpler process and equipment.
Key words: hyperbranched triazine charring agent; piperazine; synthesis; characterization; thermal stability
收稿日期： 2022-08-08
基金项目： 国家自然科学基金项目（21878165）.
作者简介： 刘文昊（1998—），男，硕士研究生 *通信联系人.
