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文章编l号： 1672-6987（2023）06-0070-06； DOI： 10.16351/j.1672-6987.2023.06.008
黄文章1， 孙琰2， 张殿奇1， 张振秀1*（1.青岛科技大学 高分子科学与工程学院，山东 青岛 266042；2. 海洋化工研究院有限公司，山东 青岛 266000）
摘要： 以胶乳海绵为基体，将海绵在气凝胶前驱体溶液中挤压浸渍，充分吸收溶胶，经老化、超临界干燥后获得具有优良隔热能力的柔性SiO2气凝胶/胶乳海绵复合材料。表征并分析了复合材料的微观结构和性能，研究了甲基三甲氧基硅烷（MTMS）的含量对隔热能力的影响，进一步探索浸渍次数对隔热及力学性能的影响。研究结果表明：当MTMS的含量（体积分数）为10%时，复合材料具有最小的导热系数。另外，在多次的浸渍处理下气凝胶布满胶乳海绵的表面和内部孔隙，成功制备出了机械性能良好、导热率达到0.038 W·(m·K)-1的SiO2气凝胶/胶乳海绵复合隔热材料。
关键词： 隔热； 超临界干燥； 气凝胶； 胶乳海绵； 连续浸渍
中图分类号： TQ 316.6文献标志码： A
引用格式： 黄文章， 孙琰， 张殿奇， 等. SiO2气凝胶/胶乳海绵复合隔热材料的制备及其性能［J］. 青岛科技大学学报(自然科学版), 2023, 44(6): 70-75.
HUANG Wenzhang， SUN Yan， ZHANG Dianqi， et al. Preparation and properties of SiO2 aerogel/latex sponge composite thermal insulation material［J］. Journal of Qingdao University of Science and Technology（Natural Science Edition), 2023， 44（6）： 70-75.
Preparation and Properties of SiO2 Aerogel/Latex Sponge
Composite Thermal Insulation Material
HUANG Wenzhang1， SUN Yan2， ZHANG Dianqi1, ZHANG Zhenxiu1
（1. College of Polymer Science and Engineering, Qingdao University of Science and Technology，
Qingdao 266042， China；2.Marine Chemical Research Institute Ltd.，Qingdao 266000， China）
Abstract: Using latex sponge as the matrix, the sponge was impregnated by extrusion in the aerogel precursor solution to fully absorb the sol, and the flexible SiO2 aerogel/latex sponge composite with excellent thermal insulation capability was obtained after aging and supercritical drying. In this study, the microstructure, mechanical properties, thermal conductivity and other aspects of the composites were characterized and analyzed. Not only the influence of methyltrimethoxysilane (MTMS) content on the thermal insulation ability, but also the thermal insulation and mechanical properties of immersion times were further explored. According to the research results, when the dispersion concentration of MTMS is 10%(volume fraction), the composite sample has the lowest thermal conductivity. In addition, the aerogel covered the surface and internal pores of the latex sponge under multiple impregnation treatments, and a SiO2 aerogel/latex sponge composite thermal insulation material with good mechanical properties and a thermal conductivity of 0.038 W·(m·K)-1 was successfully prepared.
Key words: heat insulation; supercritical drying; aerogel; latex sponge; continuous impregnation
收稿日期： 2022-11-15
基金项目： 山东省自然科学基金项目（ZR2020LFG006）.
作者简介： 黄文章 (1998-), 男, 硕士研究生.*通信联系人.
